Baumgartl, T, Chan, J, Bucka, F & Pihlap, E 2021, 'Soil organic carbon in rehabilitated coal mine soils as an indicator for soil health', in AB Fourie, M Tibbett & A Sharkuu (eds), Mine Closure 2021: Proceedings of the 14th International Conference on Mine Closure, QMC Group, Ulaanbaatar, https://doi.org/10.36487/ACG_repo/2152_121 (https://papers.acg.uwa.edu.au/p/2152_121_Baumgartl/) Abstract: Rehabilitation intends to provide a safe, stable and sustainable environment. Soil health is often used as a parameter, which describes the success of reclamation, the performance of the soil and its associated soil system functions. Reclaimed and therefore young soils are in general deprived of soil organic carbon. They are not in equilibrium with their environment and undergo changes over time, faster than natural and developed soils. Carbon content as a summarising criterion for soil health status can be used as an indicator as it reflects the performance of important soil processes, like water holding capacity, drainage and aeration potential and nutrient supply and storage. It is well established that carbon content affects soil functions like hydraulic conductivity by creating structural elements through aggregation processes. Increasing carbon content leads to increased water infiltration, reduced surface runoff and erosional risks, and increases the exchange rate of gases and improves aeration and has in general positive consequences for microbiological activity. Results from a study of soil covers of different ages emphasise this consequence. The evaluation of the rehabilitation success in coal mining using carbon content is complicated due to the difficulty distinguishing between carbon forms: organic carbon naturally formed by decomposition vs. carbon originating from coal as coal dust or charred material. Furthermore, the assessment of the performance of rehabilitated soils is strongly affected by climatic conditions, which affect the production, decomposition and translocation of organic matter. Litter and dead organic matter from plants are decomposed on the soil surface and incorporated through organisms into the soil profile. Dissolvable organic constituents may be transported with infiltrating water down the profile. Consequently, carbon is primarily concentrated close to the surface. In semi-arid environments the accumulation depth may only be centimetres as was found from a study on the performance of the carbon pool of rehabilitated soils across sites up to 35 years of age. This has implications for the sampling strategy and the assessment of the performance of soils over time. As the carbon content in soils at coal mines can be affected by precipitation and incorporation of coal dust into the soil, the content of new organic carbon representing soil health status can be misleadingly interpreted. Therefore, separation of carbon fractions is necessary to identify the “green” carbon pool (carbon originating from plant litter and residue) as best as possible and extract the correct fraction to assess the performance of soil development. A method has been developed and is presented which allows the separation between the various carbon pools. From the presented study, the following conclusions were drawn: 1) Soil carbon is an easy to measure indicator for the assessment of the performance of soil health of rehabilitated soils; 2) soil functional properties are affected by carbon content and age and hence change with soil development; 3) only green carbon represents soil health and appropriate methodology has to be in place to exclude other carbon pools; 4) carbon storage in rehabilitated soils of semi-arid environments of Australia is below that of natural soils