DOI https://doi.org/10.36487/ACG_rep/1363_10_Kolla
Cite As:
Kolla, H, Mahmoudkhani, A, Watson, P, Awad, M, O'Neill, P & Moore, L 2013, 'Next generation polymeric flocculants for thickening and dewatering', in R Jewell, AB Fourie, J Caldwell & J Pimenta (eds),
Paste 2013: Proceedings of the 16th International Seminar on Paste and Thickened Tailings, Australian Centre for Geomechanics, Perth, pp. 133-145,
https://doi.org/10.36487/ACG_rep/1363_10_Kolla
Abstract:
The management of tailings streams has taken an increasingly important role in the minerals industry in recent years. The global issue of water scarcity and tightening of regulations governing the disposal of waste waters has significantly contributed to a focus on the development of thickener technologies that is not only widely accepted but also economically advantageous. The operational desire for high density paste thickeners involves dewatering (water re-use), underflow density (pipeline transport), and stacking (deposition processes), all of which are governed by rheology. Although thickener technology has proved to be effective, in many cases, it is not efficient by itself.
The addition of chemical agents known as rheology modifiers or flocculants has shown to be instrumental in improving the overall performance efficiency of the thickening process. These flocculants are generally high molecular weight water soluble polymers that adsorb onto particle surfaces and bridge them together to form large aggregates, thus facilitating flocculation. Most of the commercially available flocculants are generically designed to perform across a broad range of mineral solids (mineralogy), but are not capable of targeting multiple performance criteria. However, a range of next-generation flocculants has been developed; these excel at multiple performance criteria for a particular mineralogy. This paper discusses the dewatering performance, stacking capability, and changes in the underflow rheology of processed gold tailings when treated with various flocculants (traditional versus next-generation).
References:
American Public Health Association (1999) Standard Methods for the Examination of Water and Wastewater, 20th Edition, American Water Works Association, Water Environment Federation, Washington, D.C.
Barnes, H.A. (1997) Thixotropy – a review, Journal of Non-Newtonian Fluid Mechanics, Vol. 70, pp. 1–33.
Berger, A., Adkins, S., Hess, S., Flanagan, I. and Stocks, P. (2011) Step change improvements in underflow rheology, in Proceedings 14th International Seminar on Paste and Thickened Tailings (Paste2011), R.J. Jewell and A.B. Fourie (eds), 5‒7 April 2011, Perth, Australia, Australian Centre for Geomechanics, Perth, pp. 135–141.
Cross, M.M. (1965) Rheology of non-Newtonian fluids: a new flow equation for pseudoplastic systems, Journal of Colloid Science, Vol. 20, pp. 417–437.
Farinato, R., Mahmoudkhani, A., Fenderson, T. and Watson, P. (2010) Segregation and differential settling in flocculated tailings, in Proceedings 2nd International Oil Sands Tailings Conference, 6–8 December, Edmonton, Canada, pp. 58–66.
Hogg, R. (1999) Polymer adsorption and flocculation, Polymers in Mineral Processing, J.S Laskowski (ed), in Proceedings UBC-McGill Bi-Annual International Symposium on Fundamentals of Mineral Processing, Quebec City, Canada, pp. 3–17.
Klein, B. and Pawlik, M. (2005) Rheology modifiers for mineral suspensions, Minerals & Metallurgical Processing, Vol. 22(2),
pp. 83–88.
Malvern Instrument Handbook (1997) Chapter 3 – How the Mastersizer works, MAN 0101, Issue 1.3, pp. 3-1–3-6.
Mensah-Addai, J. and Ralston, J. (2006) Fundamental and applied dewatering studies of clay mineral dispersions, Interfacial Phenomena in Fine Particle Technology, Z. Xu, Q. Liu, (eds), in Proceedings UBC-McGill-UA International Symposium on Fundamentals of Mineral Processing, Montreal, Canada, pp. 163–177.
Pearse, M.J. (2003) Historical use and future development of chemicals for solid-liquid separation in the mineral processing industry, Minerals Engineering, Vol. 16(2), pp. 103–108.
Pearse, M.J and Barnett, J. (1980) Chemical treatments for thickening and filtration, Filtration+Separation, Vol. 17(5), pp. 460–470.
Roussel, N., Lanos, C. and Toutou, Z. (2006) Identification of Bingham fluid flow parameters using a simple squeeze test, Journal of Non-Newtonian Fluid Mechanics, Vol. 135, pp. 1–7.
Schoenbrunn, F. (2011) Dewatering to higher densities – an industry review, in Proceedings 14th International Seminar on Paste and Thickened Tailings (Paste2011), R.J. Jewell and A.B. Fourie (eds), 5‒7 April 2011, Perth, Australia, Australian Centre for Geomechanics, Perth, pp. 19–23.
Scholz, M. (2005) Review of recent trends in capillary suction time (CST) dewaterability testing research, Ind. Eng. Chem. Res, Vol. 44, p. 8157–8167.
Slottee, S. and Biesinger, M.T. (2011) Tailings paste disposal – more than water recovery, SME Annual Meeting 2011, Denver, U.S.A., pp. 1–4.
Sofra, F. and Boger, D.V. (2011) Rheology for thickened tailings and paste – history, state-of-the-art and future directions, in Proceedings 14th International Seminar on Paste and Thickened Tailings (Paste2011), R.J. Jewell and A.B. Fourie (eds), 5‒7 April 2011, Perth, Australia, Australian Centre for Geomechanics, Perth, pp. 212–133.
Watson, P., Fenderson, T., Mahmoudkhani, A., Nair, M., Patel, A. and Roberts, G. (2011) Breakage and reformation of flocs in oil sands tailings slurries, in Proceedings Tailings and Mine Waste 2011, Vancouver, Canada, 6–9 November, pp. 293–302.